When proppant gets crushed during hydraulic fracturing, several significant issues can arise: 1. **Reduced Fracture Conductivity**: Crushed proppant can lead to a decrease in the ability of the fracture to conduct fluids. This is because the smaller, crushed particles can fill the voids between larger particles, reducing the overall permeability of the proppant pack. 2. **Increased Risk of Fracture Closure**: If the proppant is crushed, it may not be able to hold the fracture open effectively. This can lead to the fracture closing under pressure, which can significantly reduce the flow of hydrocarbons from the reservoir. 3. **Increased Operational Costs**: The need to use more proppant or to re-stimulate the well due to ineffective proppant can lead to increased operational costs. This can also result in additional time and resources spent on well completion. 4. **Potential for Well Productivity Decline**: The overall productivity of the well may decline if the proppant is not able to maintain the fracture network effectively. This can lead to lower production rates and reduced economic viability of the well. 5. **Environmental Concerns**: Crushed proppant can lead to the release of fine particles into the surrounding environment, which may pose environmental risks, including contamination of groundwater. In summary, the crushing of proppant can significantly impact the efficiency and effectiveness of hydraulic fracturing operations, leading to reduced productivity, increased costs, and potential environmental issues.
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A proppant is a solid material, typically sand, treated sand or man-made ceramic materials, designed to keep an induced hydraulic fracture open, during or following a fracturing treatment, most commonly for unconventional reservoirs. It is added to a fracking fluid which may vary in composition depending on the type of fracturing used, and can be gel, foam or slickwaterbased. In addition, there may be unconventional fracking fluids. Fluids make tradeoffs in such material properties as viscosity, where more viscous fluids can carry more concentrated proppant; the energy or pressure demands to maintain a certain flux pump rate (flow velocity) that will conduct the proppant appropriately; pH, various rheological factors, among others. In addition, fluids may be used in low-volume well stimulation of high-permeability sandstone wells (20 to 80 thousand US gallons (76 to 303 kl) per well) to the high-volume operations such as shale gas and tight gas that use millions of gallons of water per well.
Conventional wisdom has often vacillated about the relative superiority of gel, foam and slickwater fluids with respect to each other, which is in turn related to proppant choice. For example, Zuber, Kuskraa and Sawyer () found that gel-based fluids seemed to achieve the best results for coalbed methane operations,[1] but as of , slickwater treatments are more popular.
Other than proppant, slickwater fracturing fluids are mostly water, generally 99% or more by volume, but gel-based fluids can see polymers and surfactants comprising as much as 7 vol%, ignoring other additives. Other common additives include hydrochloric acid (low pH can etch certain rocks, dissolving limestone for instance), friction reducers, guar gum, biocides, emulsion breakers, emulsifiers, 2-butoxyethanol, and radioactive tracer isotopes.
Proppants have greater permeability than small mesh proppants at low closure stresses, but will mechanically fail (i.e. get crushed) and produce very fine particulates ("fines") at high closure stresses such that smaller-mesh proppants overtake large-mesh proppants in permeability after a certain threshold stress.[2]
Though sand is a common proppant, untreated sand is prone to significant fines generation; fines generation is often measured in wt% of initial feed. One manufacturer has claimed untreated sand fines production to be 23.9% compared with 8.2% for lightweight ceramic and 0.5% for their product.[3] One way to maintain an ideal mesh size (i.e. permeability) while having sufficient strength is to choose proppants of sufficient strength; sand might be coated with resin, to form curable resin coated sand or pre-cured resin coated sands. In certain situations a different proppant material might be chosen altogetherpopular alternatives include ceramics and sintered bauxite.
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Increased strength often comes at a cost of increased density, which in turn demands higher flow rates, viscosities or pressures during fracturing, which translates to increased fracturing costs, both environmentally and economically.[4] Lightweight proppants conversely are designed toals can break the strength-density trend, or even afford greater gas permeability. Proppant geometry is also important; certain shapes or forms amplify stress on proppant particles making them especially vulnerable to crushing (a sharp discontinuity can classically allow infinite stresses in linear elastic materials).[5]
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Proppant mesh size also affects fracture length: proppants can be "bridged out" if the fracture width decreases to less than twice the size of the diameter of the proppant.[2] As proppants are deposited in a fracture, proppants can resist further fluid flow or the flow of other proppants, inhibiting further growth of the fracture. In addition, closure stresses (once external fluid pressure is released) may cause proppants to reorganise or "squeeze out" proppants, even if no fines are generated, resulting in smaller effective width of the fracture and decreased permeability. Some companies try to cause weak bonding at rest between proppant particles in order to prevent such reorganisation. The modelling of fluid dynamics and rheology of fracturing fluid and its carried proppants is a subject of active research by the industry.
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Though good proppant choice positively impacts output rate and overall ultimate recovery of a well, commercial proppants are also constrained by cost. Transport costs from supplier to site form a significant component of the cost of proppants.
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Other than proppant, slickwater fracturing fluids are mostly water, generally 99% or more by volume, but gel-based fluids can see polymers and surfactants comprising as much as 7 vol%, ignoring other additives.[6] Other common additives include hydrochloric acid (low pH can etch certain rocks, dissolving limestone for instance), friction reducers, guar gum,[7] biocides, emulsion breakers, emulsifiers, and 2-Butoxyethanol.
Radioactive tracer isotopes are sometimes included in the hydrofracturing fluid to determine the injection profile and location of fractures created by hydraulic fracturing.[8] Patents describe in detail how several tracers are typically used in the same well. Wells are hydraulically fractured in different stages.[9] Tracers with different half-lives are used for each stage.[9][10] Their half-lives range from 40.2 hours (lanthanum-140) to 5.27 years (cobalt-60).[11] Amounts per injection of radionuclide are listed in The US Nuclear Regulatory Commission (NRC) guidelines.[12] The NRC guidelines also list a wide range of radioactive materials in solid, liquid and gaseous forms that are used as field flood or enhanced oil and gas recovery study applications tracers used in single and multiple wells.[12]
In the US, except for diesel-based additive fracturing fluids, noted by the American Environmental Protection Agency to have a higher proportion of volatile organic compounds and carcinogenic BTEX, use of fracturing fluids in hydraulic fracturing operations was explicitly excluded from regulation under the American Clean Water Act in , a legislative move that has since attracted controversy for being the product of special interests lobbying.[citation needed]
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